diff --git a/deepmd/tf/utils/spin.py b/deepmd/tf/utils/spin.py
index 9d1d7018fd..6e2933be17 100644
--- a/deepmd/tf/utils/spin.py
+++ b/deepmd/tf/utils/spin.py
@@ -26,6 +26,25 @@ def __init__(
         virtual_len: list[float] | None = None,
     ) -> None:
         """Constructor."""
+        # The TensorFlow spin implementation assumes spin-enabled types form a
+        # contiguous prefix of the type map: the SE-A ``sel`` extension takes the
+        # first ``ntypes_spin`` selections, and the coordinate/force splitting
+        # and bias merging address the virtual block with a dense real->virtual
+        # offset. Reject a layout where a non-spin type precedes a spin type,
+        # which would silently read the wrong real/virtual type ranges.
+        if use_spin is not None:
+            seen_non_spin = False
+            for flag in use_spin:
+                if flag:
+                    if seen_non_spin:
+                        raise ValueError(
+                            "The TensorFlow spin implementation requires "
+                            "spin-enabled types (use_spin=True) to form a prefix "
+                            f"of the type map; got use_spin={use_spin}. List all "
+                            "spin-enabled types first in the type map."
+                        )
+                else:
+                    seen_non_spin = True
         self.use_spin = use_spin
         self.spin_norm = spin_norm
         self.virtual_len = virtual_len
diff --git a/source/tests/tf/test_spin_prefix_guard.py b/source/tests/tf/test_spin_prefix_guard.py
new file mode 100644
index 0000000000..31a8ea0727
--- /dev/null
+++ b/source/tests/tf/test_spin_prefix_guard.py
@@ -0,0 +1,44 @@
+# SPDX-License-Identifier: LGPL-3.0-or-later
+"""The TF Spin helper must reject non-prefix use_spin layouts.
+
+The legacy TensorFlow spin implementation assumes spin-enabled types form a
+contiguous prefix of the type map: the SE-A ``sel`` extension takes the first
+``ntypes_spin`` selections, and the coordinate/force splitting and bias merging
+address the virtual block with a dense real->virtual offset. A non-prefix layout
+such as ``use_spin=[False, True]`` silently reads the wrong real/virtual type
+ranges (or raises deep inside the graph), so it must be rejected up front with a
+clear error.
+"""
+
+import unittest
+
+from deepmd.tf.utils.spin import (
+    Spin,
+)
+
+
+class TestSpinPrefixGuard(unittest.TestCase):
+    def test_non_prefix_rejected(self) -> None:
+        with self.assertRaises(ValueError):
+            Spin(use_spin=[False, True], spin_norm=[1.0], virtual_len=[0.4])
+
+    def test_non_prefix_rejected_middle(self) -> None:
+        with self.assertRaises(ValueError):
+            Spin(
+                use_spin=[True, False, True],
+                spin_norm=[1.0, 1.0],
+                virtual_len=[0.4, 0.4],
+            )
+
+    def test_prefix_accepted(self) -> None:
+        # spin-enabled types first: the supported layout
+        Spin(use_spin=[True, False], spin_norm=[1.0], virtual_len=[0.4])
+        self.assertEqual(Spin(use_spin=[True, True]).ntypes_spin, 2)
+
+    def test_all_non_spin_accepted(self) -> None:
+        # no spin types at all is not a non-prefix violation
+        self.assertEqual(Spin(use_spin=[False, False]).ntypes_spin, 0)
+
+
+if __name__ == "__main__":
+    unittest.main()